The University of Arizona
 

Deteriorating Negatives: A Health Hazard in
Collection Management

Summary

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Symptoms of skin and eye irritation, headache, nausea, and respiratory difficulty at ASM can be associated with one or more of the chemical compounds present in deteriorating nitrate and diacetate negatives. Interestingly, symptomatology occurs at concentrations below OSHA limits and is more pronounced as duration and possibly the level of exposure increases.

Although contaminant concentration generated by deteriorating nitrate and diacetate negatives are very low, they can be reduced further with improved ventilation controls. Improvements in general room ventilation including changes in the position of supply air registers, and the overall level of air movement will result in improved air quality through the dilution of air contaminants. However, since symptoms of exposure to contaminant exist at very low concentration, the time of exposure may also require modification. The amount of time spent working with de4teriorating negative collections will have to be determined by those involved in such activities. While improvements in ventilation are being made to reduce personal exposures, marathon work sessions of several hours or more should be avoided.

At ASM, ventilation was improved in the workroom by opening a door and turning the workstation to face the existing exhaust outlet. An exhaust hood was installed in the darkroom, with a more powerful fan and flexible duct added to exhaust fumes away from the technician and out of the work area. Protective latex gloves and respirators were worn by collection handlers. Time of exposure to materials was limited and break times for employees were lengthened. Workers were careful to wash themselves and work surfaces after each handling session. After altering handling procedures at ASM, discomfort was relieved. Conscientious efforts to maximize air movement, minimize exposure with protective clothing, and limit handling time allowed our negative conservation project to proceed safely.

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